How to use
The van’t Hoff relation describes ideal osmotic pressure for a dilute solution as proportional to effective particle count, molarity and absolute temperature.
- Enter molarity in mol/L.
- Enter temperature in °C.
- Enter van’t Hoff factor i.
- Review pressure in several units.
How it is calculated
Example
For a 0.1 M solution at 25°C with i=1, ideal osmotic pressure is about 2.45 atm.
Important notes
This is an ideal relation; concentrated or real electrolyte solutions can deviate because interactions and incomplete dissociation change the effective particle count.
Frequently asked questions
What is i?
The van’t Hoff factor approximates the effective number of dissolved particles produced per formula unit.
Why convert to Kelvin?
Gas-like thermodynamic relations use absolute temperature.
Can I use concentrated solutions?
Only as a rough ideal estimate; activity or osmotic-coefficient corrections may be needed.