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pH & pOH Calculator

Calculate pH, pOH and complementary ion concentration from H⁺ or OH⁻ concentration assuming Kw=10⁻¹⁴ near 25°C.

pH+pOH=14 is a standard dilute-water approximation near 25°C; Kw varies with temperature and medium.

How to use

pH is based on hydrogen-ion concentration and pOH on hydroxide-ion concentration. Near 25°C in dilute aqueous solutions, pH+pOH≈14.

  1. Choose H⁺ or OH⁻ input.
  2. Enter concentration in mol/L.
  3. Apply the logarithm.
  4. Review pH, pOH and complementary ion concentration.

How it is calculated

pH=−log₁₀[H⁺]; pOH=−log₁₀[OH⁻]; pH+pOH=14

Example

If [H⁺]=10⁻³ mol/L, pH=3 and pOH≈11 under the 25°C approximation.

Important notes

Concentrated/non-ideal solutions require activities rather than simple concentrations, and Kw changes with temperature.

Frequently asked questions

Is pH always 0–14?

Not necessarily for concentrated solutions; that range is common for dilute aqueous systems.

Why logarithms?

H⁺ concentrations span many orders of magnitude.

Is pH+pOH always 14?

No, 14 corresponds approximately to Kw near 25°C.